Nanoporous Cyanate Ester Resins: Structure-Gas Transport Property Relationships

Nanoporous Cyanate Ester Resins: Structure-Gas Transport Property Relationships

This contribution addresses the relationships between the structure and gas transport properties of nanoporous thermostable cyanate ester resins (CERs) derived from polycyclotrimerization of 1,1'-bis(4-cyanatophenyl)ethane in the presence of 30 or 50 wt% of inert high-boiling temperature porogens (i.e., dimethyl- or dibutyl phthalates), followed by their quantitative removal. The nanopores in t...

Nanoporous Polymer Films of Cyanate Ester Resins Designed by Using Ionic Liquids as Porogens

Novel nanoporous film materials of thermostable cyanate ester resins (CERs) were generated by polycyclotrimerization of dicyanate ester of bisphenol E in the presence of varying amounts (from 20 to 40 wt%) of an ionic liquid (IL), i.e., 1-heptylpyridinium tetrafluoroborate, followed by its quantitative extraction after complete CER network formation. The completion of CER formation and IL extra...

Final Report Cyanate Ester Composite Resins Derived from Renewable Polyphenol Sources

Effects of Chemical Structure Changes on Curing Reactions and Thermal Properties of Cyanate Ester-Cured Rigid-Rod Epoxy Resins

How chemical structure changes affect the curing reactions and thermal properties of 2,2 -bis(4-cyanatophenyl) propane (cyanate ester) cured rigid-rod epoxy resins has been studied for biphenol and tetramethyl biphenol epoxies. The formation of an oxazolidinone ring is the dominant curing reaction for biphenol epoxy, whereas the formation of a cyanurate ring is the dominant curing reaction for ...

Cyanate Ester/ TriSilanolPhenyl-POSS Nanocomposites

Kaiwen Liang, Hossein Toghiani, and Charles U. Pittman Jr. Dave C. Swalm School of Chemical Engineering, Mississippi State University, MS 39762. Department of Chemistry, Mississippi State University, MS 39762. Carbon-carbon materials are traditionally designed for high temperature applications. Carbon-carbon materials are composites formed by impregnating continuous carbon fiber cloths or prefo...